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Optimization of electrochemically synthesized Cu

Kasra Pirzadeh, Ali Asghar Ghoreyshi, Mostafa Rahimnejad, Maedeh Mohammadi

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 2,   Pages 233-247 doi: 10.1007/s11705-019-1893-1

Abstract: Cu (BTC) , a common type of metal organic framework (MOF), was synthesized through electrochemical routeTaguchi method was employed for optimization of key parameters affecting the synthesis of Cu (BTC) .using 1 g of ligand, applied voltage of 25 V, synthesis time of 2 h, and electrode length of 3 cm.The single gas sorption capacity of the synthetized microstructure Cu (BTC) for CO (at 298 K and 1Moreover, Cu (BTC) showed no considerable loss in CO adsorption after six sequential cycles.

Keywords: Cu3(BTC)2 electrochemical synthesis     CO2 adsorption     Taguchi optimization    

Preparation of Cu/ZnO/Al

Hui FAN, Huayan ZHENG, Zhong LI

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 4,   Pages 445-451 doi: 10.1007/s11705-010-0521-x

Abstract: Cu/ZnO/Al O catalysts with Cu/Zn/Al ratios of 6/3/1 were precipitated and aged by conventional and microwaveheating methods and tested in the slurry phase reactor for methanol synthesis.microwave irradiation on the catalytic performance was investigated to optimize the preparing condition of Cu

Keywords: microwave irradiation     precipitation temperature     aging temperature     methanol synthesis     Cu/ZnO/Al2O3 catalyst    

Tuning the catalytic selectivity in electrochemical CO

Jiafang XIE,Yuxi HUANG,Hanqing YU

Frontiers of Environmental Science & Engineering 2015, Volume 9, Issue 5,   Pages 861-866 doi: 10.1007/s11783-014-0742-1

Abstract: Electrochemical conversion of CO to hydrocarbons can relieve both environmental and energy stresses.By tuning the electrochemical parameters, either Cu oxide nanowires or nanoneedles were fabricated andthen electrochemically reduced to the corresponding Cu nanomaterials.The Cu nanowires preferred the formation of C H , while the Cu nanoneedles favored the production ofOur work provides a facile synthetic strategy for preparing Cu-based nanomaterials to achieve selective

Keywords: electrochemical CO2 reduction     Cu oxide     nanostructure     selectivity     hydrocarbon formation    

Preparation of Cu/ZrO

Xinmei LIU, Shaofen BAI, Huidong ZHUANG, Zifeng YAN

Frontiers of Chemical Science and Engineering 2012, Volume 6, Issue 1,   Pages 47-52 doi: 10.1007/s11705-011-1170-4

Abstract: Cu/ZrO catalysts for methanol synthesis from CO /H were respectively prepared by deposition coprecipitationand crystal structure of the catalysts are mainly controlled by preparation methods and alkalinity of synthesis

Keywords: Cu/ZrO2     methanol synthesis     deposition coprecipitation     solid state reaction     CO2/H2    

Advantageous mechanochemical synthesis of copper(I) selenide semiconductor, characterization, and properties

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 3,   Pages 433-442 doi: 10.1007/s11705-021-2066-6

Abstract: measurements of milled 2Cu/Se mixtures.The X-ray diffraction confirmed the orthorhombic crystal structure of Cu2Se with the crystallite2p and Se 3d signals corresponded to Cu+ and Se2 oxidation states.This type of Cu2Se synthesis can be easily adapted to production dimensions using an industrial, and waste-free manufacturing of Cu2Se.

Keywords: Cu2Se     berzelianite     nanocrystalline semiconductor     mechanochemical synthesis     planetary ball    

An investigation of the CHOH and CO selectivity of CO hydrogenation over Cu–Ce–Zr catalysts

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 6,   Pages 950-962 doi: 10.1007/s11705-022-2162-2

Abstract: 2 to CO/CH3OH products.The Cu–Ce–Zr catalyst with 2 wt% Ce loading shows higher CO selectivity (SCO = 0.0%–87.8%) from 200–300 °C, while the Cu–Ce–Zr catalyst with 8 wt% Ce loading presents higher CO22 adsorption step, a larger number of hydroxyl groups over the Cu–Ce–Zr catalystHence, the Cu–Ce–Zr catalyst with 8 wt% Ce loading favors CH3OH selectivity and CO2

Keywords: CO2 hydrogenation     Cu–Ce–Zr     hydroxyls     CO/CH3OH selectivity    

A Cu-modified active carbon fiber significantly promoted HS and PH simultaneous removal at a low reaction

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 6, doi: 10.1007/s11783-021-1425-3

Abstract:

Cu0.15-ACF performs the best for H2S and PH3 simultaneous removal.

Keywords: ACF     H2S     PH3     Cu     Low temperature     Simultaneous removal    

Improvement in the synthesis of 2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid 2-benzothiazolyl

GAO Shihao, SUN Chenghui, ZHAO Xinqi, GAO Changquan

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 1,   Pages 80-84 doi: 10.1007/s11705-008-0017-0

Abstract: 2-(5-Amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid 2-benzothiazolyl thioester(III), an importantintermediate of the fourth generation cephalosporins, was efficiently synthesized by reacting 2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid (I) with 2,2′-dibenzothiazole disulfide (II) in

Keywords: 5-Amino-1     2     4-thiadiazol-3-yl     1     2-dichloroethane     important intermediate     2-benzothiazolyl thioester     temperature    

Synthesis of copolymers of 3-acryloyloxymethyl-3′-methyloxetane and 3-(2-(2-(2-Methoxyethylenoxy)ethylenoxy)ethylenoxy)-3′-methyloxetane and their ionic conductivity properties

YE Lin, ZHAO Yumei, FENG Zengguo, BAI Ying, WU Feng

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 4,   Pages 343-348 doi: 10.1007/s11705-007-0062-0

Abstract: An oxetane-derived monomer, 3-acryloyloxymethyl-3′-methyloxetane (AMO) was prepared from the reactionof 3-hydromethyl-3-methyloxetane with acryloyl chloride.The cationic ring-opening copolymerization of AMO with another oxetane-derived monomer, 3-(2-(2-(2-methoxyethylenoxy)ethylenoxy)ethylenoxy)-3′-methyloxetane (MEMO) was conducted in CHCl solution using BF3 ·OEt/1, 4-butanediol

Keywords: 4-butanediol     2-methoxyethylenoxy     consistent     oxetane-derived     copolymer    

Plasma-electrochemical synthesis of europium doped cerium oxide nanoparticles

Liangliang Lin, Xintong Ma, Sirui Li, Marly Wouters, Volker Hessel

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 3,   Pages 501-510 doi: 10.1007/s11705-019-1810-7

Abstract: In the present study, a plasma-electrochemical method was demonstrated for the synthesis of europiumDue to the simple, flexible and environmental friendly process, this plasma-electrochemical method shouldhave great potential for the synthesis of a series of nanophosphors, especially for bio-application

Keywords: plasma-electrochemical method     europium doped ceria     rare earth nanoparticles     photoluminescence    

Catalytic hydrolysis of gaseous HCN over Cu–Ni/γ-Al

Linxia Yan, Senlin Tian, Jian Zhou, Xin Yuan

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 6, doi: 10.1007/s11783-016-0872-8

Abstract: The Cu–Ni/γ-Al O catalyst was prepared to study HCN hydrolysis ?To decompose efficiently hydrogen cyanide (HCN) in exhaust gas, g-Al O -supported bimetallic-based Cu–Nivolume ratio, reaction temperature, and the presence of CO or O on the HCN removal efficiency on the Cu–Ni

Keywords: Hydrogen cyanide     Cu–Ni/g-Al2O3     Catalytic hydrolysis    

Large-scale synthesis of isolated Mn2O3 nanotube/fiber with ferric nitrate as catalyst

ZHANG Aifei, LIU Jiping, L? Guangshu

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 1,   Pages 55-58 doi: 10.1007/s11705-007-0011-y

Abstract: Isolated MnO nanotubes and nanofibers were prepared very easily at a large scale with the liquid-phase catalysis method. The MnO nanotubes had dimensions of 30 50 nm (exterior diameter) and 0.2 1.0 ?m (length), approximately. The O nanofibers had dimensions of 10 30 nm (diameter) and 0.4 2.0 ?m (length), approximately. Nano-O with different microstructures including nanotubes, nanofibers and nanoparticles could be selectively synthesized by controlling the contents and proportions of potassium permanganate and ferric nitrate. Ferric nitrate was an ideal catalyst for the preparation of O nanotube/fiber. When cobalt nitrate or nickel nitrate was used as catalyst, only amorphous nano-O was synthesized. X-ray diffraction (XRD) result shows that the O nanotube has a crystalline structure different from o-O, t-O, h-O and ?-O.

Keywords: different     nickel     exterior diameter     nanotube     XRD    

Synthesis and anticancer activity of (+)-nopinone-based 2-amino-3-cyanopyridines

Shengliang LIAO,Shibin SHANG,Minggui SHEN,Xiaoping RAO,Hongyan SI,Jie SONG,Zhanqian SONG

Frontiers of Agricultural Science and Engineering 2015, Volume 2, Issue 4,   Pages 335-340 doi: 10.15302/J-FASE-2015079

Abstract: Twelve (+)-nopinone-based 2-amino-3-cyanopyridines 4a–l were synthesized from (–)-β-pinene.

Keywords: b-pinene     nopinone     synthesis     2-amino-3-cyanopyridine     anticancer    

Microwave-assisted synthesis and antimicrobial activities of 2-aryl-3-(naphthalene-1 or 2-yl)-1,3-thiazolidin

Hua CHEN, Yanan LI, Jie BAI, Lian ZHAO, Xiangguo YUAN, Xiaoliu LI, Keqiang CAO

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 2,   Pages 186-191 doi: 10.1007/s11705-009-0004-0

Abstract: 2-aryl-3-(naphthalene-1 or 2-yl)-1,3-thiazolidin-4-ones and were synthesized in 41%-67% yield by

Keywords: microwave-assisted synthesis     naphthyl     thiazolidin-4-one     antimicrobial    

Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr2O3 Systemwith Al2O3 and Cr2O3 Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Strategic Study of CAE 2004, Volume 6, Issue 6,   Pages 63-67

Abstract:

The thermodynamic calculation and analysis of combustion synthesis reaction of Al - Cr<sub>2</sub>O<sub>3</sub> system with AI<sub>2</sub>O<sub>3</sub>and Cr<sub>2</sub>O<sub>3</sub> diluents were conducted, and the effects of reactionstarting temperature T<sub>O</sub>, diluents AI<sub>2</sub>O<sub>3</sub> and Cr<sub>2</sub>O<sub>3</sub> on the adiabatic combustion temperature

Keywords: cermet     combustion synthesis     Al - Cr2O3 system     thermodynamics     reaction model    

Title Author Date Type Operation

Optimization of electrochemically synthesized Cu

Kasra Pirzadeh, Ali Asghar Ghoreyshi, Mostafa Rahimnejad, Maedeh Mohammadi

Journal Article

Preparation of Cu/ZnO/Al

Hui FAN, Huayan ZHENG, Zhong LI

Journal Article

Tuning the catalytic selectivity in electrochemical CO

Jiafang XIE,Yuxi HUANG,Hanqing YU

Journal Article

Preparation of Cu/ZrO

Xinmei LIU, Shaofen BAI, Huidong ZHUANG, Zifeng YAN

Journal Article

Advantageous mechanochemical synthesis of copper(I) selenide semiconductor, characterization, and properties

Journal Article

An investigation of the CHOH and CO selectivity of CO hydrogenation over Cu–Ce–Zr catalysts

Journal Article

A Cu-modified active carbon fiber significantly promoted HS and PH simultaneous removal at a low reaction

Journal Article

Improvement in the synthesis of 2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid 2-benzothiazolyl

GAO Shihao, SUN Chenghui, ZHAO Xinqi, GAO Changquan

Journal Article

Synthesis of copolymers of 3-acryloyloxymethyl-3′-methyloxetane and 3-(2-(2-(2-Methoxyethylenoxy)ethylenoxy)ethylenoxy)-3′-methyloxetane and their ionic conductivity properties

YE Lin, ZHAO Yumei, FENG Zengguo, BAI Ying, WU Feng

Journal Article

Plasma-electrochemical synthesis of europium doped cerium oxide nanoparticles

Liangliang Lin, Xintong Ma, Sirui Li, Marly Wouters, Volker Hessel

Journal Article

Catalytic hydrolysis of gaseous HCN over Cu–Ni/γ-Al

Linxia Yan, Senlin Tian, Jian Zhou, Xin Yuan

Journal Article

Large-scale synthesis of isolated Mn2O3 nanotube/fiber with ferric nitrate as catalyst

ZHANG Aifei, LIU Jiping, L? Guangshu

Journal Article

Synthesis and anticancer activity of (+)-nopinone-based 2-amino-3-cyanopyridines

Shengliang LIAO,Shibin SHANG,Minggui SHEN,Xiaoping RAO,Hongyan SI,Jie SONG,Zhanqian SONG

Journal Article

Microwave-assisted synthesis and antimicrobial activities of 2-aryl-3-(naphthalene-1 or 2-yl)-1,3-thiazolidin

Hua CHEN, Yanan LI, Jie BAI, Lian ZHAO, Xiangguo YUAN, Xiaoliu LI, Keqiang CAO

Journal Article

Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr2O3 Systemwith Al2O3 and Cr2O3 Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Journal Article